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Washburn's equation
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Washburn's equation : ウィキペディア英語版
Washburn's equation
In physics, Washburn's equation describes capillary flow in a bundle of parallel cylindrical tubes; it is extended with some issues also to imbibition into porous materials. The equation is named after Edward Wight Washburn; also known as Lucas–Washburn equation, considering that Richard Lucas wrote a similar paper three years earlier, or the Bell-Cameron-Lucas-Washburn equation, considering J.M. Bell and F.K. Cameron's discovery of the form of the equation fifteen years earlier.
==Derivation==
In case of a fully wettable capillary, it is
:
L^2=\frac
where t is the time for a liquid of dynamic viscosity \eta and surface tension \gamma to penetrate a distance L into the capillary whose pore diameter is D.
In case of a porous materials many issues have been raised both about the physical meaning of the calculated pore diameter D and the real possibility to use this equation for the calculation of the contact angle of the solid.
The equation is derived for capillary flow in a cylindrical tube in the absence of a gravitational field, but is sufficiently accurate in many cases when the capillary force is still significantly greater than the gravitational force.
In his (paper ) from 1921 Washburn applies Poiseuille's Law for fluid motion in a circular tube. Inserting the expression for the differential volume in terms of the length l of fluid in the tube dV=\pi r^2 dl, one obtains
:\frac=\frac(r^4 +4 \epsilon r^3)
where \sum P is the sum over the participating pressures, such as the atmospheric pressure P_A, the hydrostatic pressure P_h and the equivalent pressure due to capillary forces P_c. \eta is the viscosity of the liquid, and \epsilon is the coefficient of slip, which is assumed to be 0 for wetting materials. r is the radius of the capillary. The pressures in turn can be written as
:P_h=h g \rho - l g \rho\sin\psi
:P_c=\frac\cos\phi
where \rho is the density of the liquid and \gamma its surface tension. \psi is the angle of the tube with respect to the horizontal axis. \phi is the contact angle of the liquid on the capillary material. Substituting these expressions leads to the first-order differential equation for
the distance the fluid penetrates into the tube l:
:\frac=\frac\cos\phi )(r^4 +4 \epsilon r^3)}

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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